Elongated and substituted triazine-based tricarboxylic acid linkers for MOFs

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Elongated and substituted triazine-based tricarboxylic acid linkers for MOFs

New triazine-based tricarboxylic acid linkers were prepared as elongated relatives of triazinetribenzoic acid (TATB). Additionally, functional groups (NO2, NH2, OMe, OH) were introduced for potential post-synthetic modification (PSM) of MOFs. Functionalized tris(4-bromoaryl)triazine "cores" (3a,3b) were obtained by unsymmetric trimerization mixing one equivalent of an acid chloride (OMe or NO2 ...

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ژورنال

عنوان ژورنال: Beilstein Journal of Organic Chemistry

سال: 2016

ISSN: 1860-5397

DOI: 10.3762/bjoc.12.219